The aim of strategy alignment in knowledge management value chain is to create and develop strategies for knowledge management in organization in order to align and overlap with grant organizational strategy. So this strategy should guide all organizational resources to create added value and achieve to competitive advantage. This paper tries, through defining and elaborating the concept of value chain in knowledge management process, as well as describing each section of that in detail, to give an strategic model on this process. Then the relation of this strategy with main organizational strategy is developed and analyzed as an integrated model.